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queen bee Blair Waldorf, played by Leighton Meester, had a fling with college student and socialite Carter Baizen, played by Sebastian Stan.

Though Baizen only appeared in 11 episodes of the series, Stan went on to date Meester in real life for two years, from 2010 to 2012.

It was my choice to breakup, but I love her as a friend. I will continue to be her friend and be there for her." Except, well, he wasn't.

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Co-star Geoffrey Arend admitted the cast had heard rumors that Daly and Leoni were more than just colleagues, but noted, "Nobody really knew [they were dating].

Jonas told , "Demi and I knew going into our romantic relationship that it may not be an easy one.

I realize over the time we have shared together that I feel I care more about our friendship right now.

They continued to play a couple on-screen until the series ended in 2012, but neither one of them is bitter: Badgley actually told ) that shooting scenes with her in Iceland were his favorite moments of the entire series "because the country is beautiful, because the Northern Lights are magical, and because it was there that I fell in love.

If you're already attracted to someone, and then they play your love interest in the show, it becomes very easy to fall in love." that ironically, it was gossip that led to their eventual split in 2010: Westwick dumped the brunette beauty after he heard through the grapevine that Szohr was allegedly getting flirty with one of his best friends.